Structural,optical and electrical properties of indium doped Cu2ZnSn(S,Se)4 thin films synthesized by the DC and RF reactive magnetron cosputtering

Element doping into the Cu₂ZnSn(S,Se)₄ (CZTSSe) absorber is an effective method to optimize the performance of thin film solar cells. In this study, the Cu₂In_xZn_1-xSn(S,Se)₄ (CIZTSSe) precursor film was deposited by magnetron cosputtering technique using indium (In) and quaternary Cu₂ZnSnS₄ (CZTS) as targets. Meanwhile, the In content was controlled using the direct current (DC) power on In target (P_In). A single kesterite CIZTSSe alloy was formed by successfully doping a small number of In³⁺ into the main lattice of CZTSSe. The partial Zn²⁺ cations were substituted by In³⁺ ions, resulting in improving properties of CZTSSe films. Morphological analysis showed that large grain CIZTSSe films could be obtained by doping In. The well-distributed, smooth, and dense film was obtained when the P_In was 30 W. The band gap of CIZTSSe could be continuously adjusted from 1.27 to 1.05 eV as P_In increased from 0 to 40 W. In addition, the CIZTSSe alloy thin film at P_In = 30 W exhibited the best p-type conductivity with Hall mobility of 6.87 cm²V^?1s^?1, which is a potential material as the absorption layer of high-performance solar cells.     

滑动式Lagrange插值法在BDS星历插值中的应用分析

该文利用滑动式Lagrange插值算法,从三个方面对BDS三种星历进行了内插精度分析,并与传统La-grange插值算法做了比较.首先对比相同阶数下两种算法的非端点处插值结果的精度;其次考虑端点龙格现象,分析两种方法的端点插值结果的精度;最后根据计算结果的均方根误差,分析插值结果整体精度的大小,并采用BDS精密星历数据进行验证.研究结果表明,滑动式Lagrange插值算法的插值精度较高,且误差分布均匀,最高可达亚毫米级别.该方法较好地适用于BDS星历的内插.     

Visual Detection of Adenosine Triphosphate by Taylor Rising: A Simple Point-of-Care Testing Method Based on Rolling Circle Amplification

Rapid and sensitive point-of-care testing (POCT) is an extremely critical mission in practical applications, especially for rigorous military medicine, home health care, and in the third world. Here, we report a visual POCT method for adenosine triphosphate (ATP) detection based on Taylor rising in the corner of quadratic geometries between two rod surfaces. We discuss the principle of Taylor rising, demonstrating that it is significantly influenced by contact angle, surface tension, and density of the sample, which are controlled by ATP-dependent rolling circle amplification (RCA). In the presence of ATP, RCA reaction effectively suppresses Taylor-rising behavior, due to the increased contact angle, density, and decreased surface tension. Without addition of ATP, untriggered RCA reaction is favorable for Taylor rising, resulting in a significant height. With this proposed method, visual sensitive detection of ATP without the aid of other instruments is realized with only a 5 μL droplet, which has good selectivity and a low detection limit (17 nM). Importantly, this visual method provides a promising POCT tool for user-friendly molecular diagnostics.     

Revamping SiO2 Spheres by Core–Shell Porosity Endowment to Construct a Mazelike Nanoreactor for Enhanced Catalysis in CO2 Hydrogenation to Methanol

Beyond the catalytic activity of nanocatalysts, the support with architectural design and explicit boundary could also promote the overall performance through improving the diffusion process, highlighting additional support for the morphology-dependent activity. To delineate this, herein, a novel mazelike-reactor framework, namely multi-voids mesoporous silica sphere (MVmSiO₂), is carved through a top-down approach by endowing core-shell porosity premade Stöber SiO₂ spheres. The precisely-engineered MVmSiO₂ with peripheral one-dimensional pores in the shell and interconnecting compartmented voids in the core region is simulated to prove combined hierarchical and structural superiority over its analogous counterparts. Supported with CuZn-based alloys, mazelike MVmSiO₂ nanoreactor experimentally demonstrated its expected workability in model gas-phase CO₂ hydrogenation reaction where enhanced CO₂ activity, good methanol yield, and more importantly, a prolonged stable performance are realized. While tuning the nanoreactor composition besides morphology optimization could further increase the catalytic performance, it is accentuated that the morphological architecture of support further boosts the reaction performance apart from comprehensive compositional optimization. In addition to the found morphological restraints and size-confinement effects imposed by MVmSiO₂, active sites of catalysts are also investigated by exploring the size difference of the confined CuZn alloy nanoparticles in CO₂ hydrogenation employing both in-situ experimental characterizations and density functional theory calculations.     

全自动平面口罩机质量状况分析

佩戴口罩是目前人民群众预防新型冠状病毒的主要途径之一,口罩生产设备的质量直接关系到口罩的产能、质量和生产安全.介绍了新冠疫情以来口罩机行业的现状,并结合全自动平面口罩机的结构特点,对其使用性能和机械安全的质量状况进行分析;指出在使用性能方面,主要存在口罩片滚切不齐、多切、少切、斜切、鼓形切边、波浪切边及耳带错焊、漏焊、耳带纠缠等问题;在机械安全方面主要存在不符合机械安全通用标准的情况;同时分析了造成这些问题的主要原因并提出了改进建议.为口罩机行业的生产提供借鉴和参考,以提高这类设备的整体质量水平.     

以管理提升实现财务价值

引言2020年6月13日,国务院国资委制定印发了《关于开展对标世界一流管理提升行动的通知》,提出以对标世界一流为出发点和切入点,以加强管理体系和管理能力建设为主线,用2~3年的时间,推动部分中央企业和地方国有重点企业管理达到或接近世界一流水平。     

Research on the hydrogen injection strategy of a direct injection natural gas/hydrogen rotary engine considering apex seal leakage

The purpose of the present paper is to investigate the hydrogen injection strategy on the combustion performance of a natural gas/hydrogen rotary engine. Considering that apex seal leakage (ASL) is an inevitable problem in the actual working process of a rotary engine, the action of ASL cannot be ignored for an in-depth study of its combustion performance. Therefore, in this paper, a 3D dynamic simulation model that put the effect of ASL into consideration was established. Furthermore, based on the established 3D model, the combustion process of a natural gas/hydrogen rotary engine under various hydrogen injection angle (HIA) and hydrogen injection timing (HIT) was investigated. The results indicated that the hydrogen jet flow first impacted on the rotor wall after entering the cylinder, and then diffused under the action of the vortexes in the cylinder. Therefore, the HIA and HIT could change the hydrogen distribution by changing the hydrogen impact location and the intensities of the vortexes in the cylinder. In addition, the ideal hydrogen distribution at the ignition timing which could improve the combustion efficiency was given. That is, under the premise of ensuring minimized hydrogen leakage, the hydrogen should mainly distribute in the middle and the front of the cylinder, and a high hydrogen concentration is maintained near the spark plug.     

Design and synthesis of side-chain optimized poly(2,6-dimethyl-1,4-phenylene oxide)-g-poly(styrene sulfonic acid) as proton exchange membrane for fuel cell applications: Balancing the water-resistance and the sulfonation degree

Side-chain optimized poly (2,6-dimethyl-1,4-phenylene oxide)-g-poly (styrene sulfonic acid) (PPO-g-PSSA) is designed with balanced water-resistance and sulfonation degree. The PPO-g-PSSA is synthesized by controlled atom-transfer radical polymerization (ATRP) from brominated poly (2,6-dimethyl-1,4-phenylene oxide) (PPO-xBr) and ethyl styrene-4-sulfonate and followed by hydrolysis. A series of PPO-g-PSSA are prepared possessing different bromination degree (x) of PPO-xBr and polymerization degree (m) of the side-chains and the water-resistances of the fabricated membranes are investigated. The results show that a PPO-g-PSSA at relatively low x (x < 0.2) and high m (m > 4) exhibits good balance between the water-resistance and the sulfonation degree. Namely, it displays suitable proton conductivity with compromised water-resistance. Moreover, a maximum ion exchange capacity (IEC) of 3.24 mmol g^?1 is reached without the sacrifice of water-resistance. In addition, PPO-g-0.08PSSA-13 and PPO-g-0.14PSSA-4 are chosen characterized by thermogravimetric analysis, proton conductivities and mechanical properties. At 90% RH, the optimized PPO-g-0.08PPSA-13 possesses a proton conductivity of 37.9 mS cm^?1 at 40 °C and 45.5 mS cm^?1 at 95 °C, respectively.     

Chromium evaporation and oxidation characteristics of alumina-forming austenitic stainless steels for balance of plant applications in solid oxide fuel cells

The chromium (Cr) evaporation behavior of several different types of iron (Fe)-based AFA alloys and benchmark Cr₂O₃-forming Fe-based 310 and Ni-based 625 alloys was investigated for 500 h exposures at 800 °C to 900 °C in air with 10% H₂O. The Cr evaporation rates from alumina-forming austenitic (AFA) alloys were ~5 to 35 times lower than that of the Cr₂O₃-forming alloys depending on alloy and temperature. The Cr evaporation behavior was correlated with extensive characterization of the chemistry and microstructure of the oxide scales, which also revealed a degree of quartz tube Si contamination during the test. Long-term oxidation kinetics were also assessed at 800 to 1000 °C for up to 10,000 h in air with 10% H₂O to provide further guidance for SOFC BOP component alloy selection.     

Parameter identification of proton exchange membrane fuel cell via Levenberg-Marquardt backpropagation algorithm

It is essential to develop an accurate model of proton exchange membrane fuel cell (PEMFC) for a reliable operation and analysis, in which unknown parameters usually need to be determined. The inherent nonlinear, strong coupling, and diversification of PEMFC model seriously hinder traditional methods to identify the parameters. For the sake of overcoming these thorny obstacles, Levenberg-Marquardt backpropagation (LMBP) algorithm based on artificial neural networks (ANNs) is proposed for PEMFC parameter identification. Furthermore, the performance of LMBP is thoroughly evaluated and compared with four typical meta-heuristic algorithms under three cases. Simulation results indicate that LMBP performs a higher accuracy and faster speed for parameter identification. In particular, accuracy and convergence speed can achieve as much as 99.8% and 95.9% growth via LMBP, respectively.